Rayleigh instability electrospinning pdf

If the jet turns into very fine fibers instead of breaking into small droplets, the process is known as electrospinning. Rayleighinstabilitydriven morphology transformation of electrospun polymer fibers imaged by in situ optical microscopy and stimulated raman scattering microscopy. Electrospinning of polymeric nanofibers for tissue. Pdf electrospinning of nanofibers and the charge injection method. Tens of thousands of researchers have been involved in electrospinning. Subms dynamics of the instability onset of electrospinning. He showed that the whipping instability in downward electrospinning process is due to slight air perturbation that leads to initiation of oscillation of small amplitude. A variety of techniques can be used for creating polymeric nanofibers such as drawing, template synthesis, selfassembly, phase separation, and electrospinning. This instability becomes more important as the diameter of the jet becomes smaller. The path of the jet is from a fluid surface that is often, but not necessarily constrained by an orifice, through a straight segment of a tapering cone, then through a series of successively smaller electrically driven bending coils, with each bending coil having turns of increasing. However, only the initial thickness and primary thinning of the jet can be quantitatively evaluated using such images. Introduction of physical principles of electrospinning technology taylor cone, rayleigh instability, needle electrospinning, needleless electrospinning, etc. The outcome of electrospinning becomes evident only after analysing under microscope the weblike structure collected on. We also perform a parametric study about both the average velocity fig.

Rayleigh 8 and, later, zeleny,9 the electrospinning process relies on a. This instability would occur when the energy of one or more isolated droplets on the surfaces is less than that of the. Electrospinning is a process in which solid fibers are produced from a polymeric fluid stream solution or melt delivered through a millimeterscale nozzle. Pdf electrospinning jets and polymer nanofibers researchgate. The other instabilities acting on the jet during electrospinning and in. Bending instability in electrospinning of nanofibers. Allometric scaling and instability in electrospinning.

Yarin faculty of mechanical engineering, technion, haifa 32000, israel s. Israelachvili, in intermolecular and surface forces third edition, 2011. Electrospinning of nanofibers subbiah 2005 journal of. Experiments and modelling of electrospinning process. These instabilities were shown to vary along the path depending upon the fluid parameters and the operating conditions. The susceptibility of the jet to the rayleigh instability was examined in two ways. Rayleighinstabilitydriven morphology transformation of electrospun. Polymerfree electrospinning of tannic acid and cross. Renekera maurice morton institute of polymer science, department of polymer science, the university of akron. Neves1,2 electrospinning has attracted tremendous interest in the research community as a simple and versatile technique to produce synthetic polymeric ultrafine fibres with diameters ranging from a few micrometres to tens of nanometres. Electrospinning jets and nanofibrous structures ncbi.

Apr 28, 2000 nanofibers of polymers were electrospun by creating an electrically charged jet of polymer solution at a pendent droplet. In the timeline of electrospinning, rayleigh in 1897 first observed it, which. Surface free energy analysis of electrospun fibers based. Fiber formation in electrospinning is governed by two instabilities acting on the polymer solution jet. Rayleighinstabilitydriven morphology transformation by thermally. This technique is applicable to virtually every soluble or fusible polymer and is capable of spinning fibers in a variety of shapes and sizes with a wide range of properties to be used in a broad range of biomedical and industrial applications. Threedimensional model for electrospinning processes in. Bending instability of electrically charged liquid jets of polymer solutions in electrospinning darrell h. Nanofibers of polymers were electrospun by creating an electrically charged jet of polymer solution at a pendent droplet.

Electrospinning is a straightforward method to produce submicrometer or nanoscale fiber. Electrospinning technology for nanofiber production 4spin. Rayleigh instability and the hysteresis between the onset and disruption of a. Following the pioneering works of rayleigh8 and, later, zeleny,9 the electrospinning. These are the axisymmetric varicose instability rayleigh. Yarin technionisrael institute of technology, haifa 32000, israel hao fong and sureeporn koombhongse. The process does not require the use of coagulation chemistry or high temperatures to. Production of coreshell fibers by electrospinning from a. Polycaprolactone pcl, an important polymer in biomedical applications, has been electrospun in several solvent systems. N,ndimethylformamide dmf is often used as an additive in the solvent system to prepare pcl nanofibers. Electrospinning shares characteristics of both electrospraying and conventional solution dry spinning of fibers. The rayleigh plateau instability is defined by two factors.

Pdf in electrospinning, polymer nanofibers are formed by the creation and elongation of an. A ssuming spinneret is given a positive charge unless otherwise stated. Production of coreshell fibers by electrospinning from a free sur face the mit faculty has made this article openly available. The solid fibers are notable for their very small diameters electrospinning. The rayleighplateau instability is defined by two factors. The axisymmetric rayleigh instability is dominated by surface tension and is suppressed at high electric fields or charge densities. Rayleigh force acts on the jet on opposite sides perpendicular to the surface area of the jet while surface tension. It is called the rayleigh instability rayleigh, 1945. Rayleighinstabilitydriven morphology transformation of.

Production of coreshell fibers by electrospinning from a free sur face. In recent years, electrospinning has become of great interest, not only because it can produce polymer fibers with diameters in the range of nano to. Surface free energy analysis of electrospun fibers based on. To obtain good quality nanofibers one should always take great care of such instabilities. The keyhole tends to be closed at some parts along the penetration.

Jul 12, 2012 rayleigh instability driven morphology transformation of electrospun polymer fibers imaged by in situ optical microscopy and stimulated raman scattering microscopy. The plateau rayleigh instability, often just called the rayleigh instability, explains why and how a falling stream of fluid breaks up into smaller packets with the same volume but less surface area. Jan 20, 2010 in recent years, electrospinning has become of great interest, not only because it can produce polymer fibers with diameters in the range of nano to a few micrometers using polymer solutions or. In situ optical microscopy and stimulated raman scattering srs microscopy are used to observe the transformation process, which is driven by the rayleigh instability, the surface tensions, and the interfacial tensions of polymers. His ideas later became known as the leaky dielectric model.

Hohman james franck institute and department of physics, university of chicago, chicago, illinois 60637 m. Rayleighinstabilitydriven morphology transformation of electrospun polymer fibers imaged by in situ optical microscopy and stimulated. Surface modification to form anisotropic polymer particles driven by the plateaurayleigh instability as fluorescence manipulation platforms, macromolecules, 10. It is related to the rayleigh taylor instability and is part of a greater branch of fluid dynamics concerned with fluid thread breakup. In the timeline of electrospinning, rayleigh in 1897 first observed it, which was later studied by zeleny in 1914 as electrospraying and was patented by formhals in 1934. Electrospun coreshell fibers have great potentials in many areas, such as tissue engineering, drug delivery, and organic solar cells. The name electrospray is used for an apparatus that employs electricity to disperse a liquid or for the fine aerosol resulting from this process. Electrospray and electrospinning theory first proposed by bose in 1745, the research of electrospray went through a slow development period until the rayleigh limit, which accurately predicts the maximum amount of. The length scale, shown in fig 2, is the length over which the fluid begins to decompose into droplets. Electrospinning of polycaprolatone nanofibers with dmf. Evolution of a rayleigh taylor instability of a lessdense waste layer, due to retained gas bubbles depicted as blue spheres, rising in a moredense layer. May 28, 2016 electrospinning is a straightforward method to produce submicrometer or nanoscale fiber. This point is associated with the electrostatic rayleigh criterion.

The regulation of scale and bifurcationlike instability in electrospinning are intriguing and enduring problems after the technology was invented by formhals in 1934. However, environmental problems, especially global warming and pollution, due to the consumption of. Nanotechnology, which is expected to meet the increasing demand for energy, has been widely used in engineering, biology, physics and chemistry for various applications. Sep 23, 2010 electrospinning of nanofibers slideshare uses cookies to improve functionality and performance, and to provide you with relevant advertising. The plateaurayleigh instability is named for joseph plateau and lord rayleigh. Electrospinning is a method based on the use of electrostatic forces for producing continuous fi bres with the diameter from between ten nanometres to some micrometres. Electrospinning is an old but yet fascinating technique. Production of coreshell fibers by electrospinning from a free surface. After the jet flowed away from the droplet in a nearly straight line, it be. With the advancement of nanotechnology and the popularity of the electrospinning process, several other mathematical models were devel. Over the past few years, this technology has shown excellent application to the production of novel energy materials 24. Study of polycaprolactone wet electrospinning process. Electrospinning is the process of choice allowing the preparation of nanofibrous materials from a solution usually based on a high molar mass polymer.

In 1873, joseph plateau rst studied the instability of liquid cylinders. Electrospinning is a process that creates nanofibers through an electrically charged jet of polymer solution or melt. If you continue browsing the site, you agree to the use of cookies on this website. Electrospinning is one of the most common methods to prepare polymer fibers with sizes ranging from several nanometers to hundreds of micrometers.

First, a deborah number was defined as the ratio of the fluid relaxation time to the instability growth time and was shown to correlate with the arrest of droplet breakup, giving rise to electrospinning rather than electrospraying. Yujing chiu, chihting liu, changching weng, tangyao chiu, jiawei li and jiuntai chen, sunnysideup eggshaped structures. Experimental validation of upward electrospinning process. From electrospun coreshell polymer fibers to polymer microbowls. Subms dynamics of the instability onset of electrospinning martina montinaro,a vito fasano,a maria mo. Even though electrospinning is a novel method for sensor surface modification, its an old technique that has been the basis for theoretical studies and new applications for more than a hundred years. Jul 16, 2001 electrospinning is a process in which solid fibers are produced from a polymeric fluid stream solution or melt delivered through a millimeterscale nozzle. Yu examined the effect of fluid elasticity on rayleigh instability. Electrospinning is one of the most common methods to prepare polymer. After travelling certain distance, produced jet is susceptible to various instabilities e. The solution must bring enough chain entanglements to avoid any breaking or rayleigh instability of the electrospun jet resulting thus in.

This instability usually appears in the electrospinning of extremely dilute polymer solutions, where the resultant droplet forma tions are described as a pearl effect on the fibers, beadsonastring, or simply as polymer beads 15. The adding of the dmf changes the physical properties of the solution. Rayleigh instability an overview sciencedirect topics. Electrospinning is a fiber production method which uses electric force to draw charged threads of polymer solutions or polymer melts up to fiber diameters in the order of some hundred nanometers. Rayleighinstabilitydriven morphology transformation by. Electrospinning jets and polymer nanofibers sciencedirect. Rayleigh instability driven morphology transformation of electrospun polymer fibers imaged by in situ optical microscopy and stimulated raman scattering microscopy.

Free surface electrospinning of aqueous polymer solutions. In most studies of electrospun polymer fibers, the properties and morphologies of polymer fibers are controlled by changing the electrospinning conditions. In electrospinning, polymer nanofibers are formed by the creation and elongation of an electrified fluid jet. The rayleigh limit, taylor cone, perturbations, and instabilities are the theoretical backgrounds of the electrospinning process 9,10,12. When the keyhole is being closed by instability, the laser beam strongly interacts with the molten metal at the closing part and opens the keyhole again by high recoil pressure as shown in fig. Electrospinning is a widely used technique for the electrostatic production of nanofibers, during which electric power is used to make polymer fibers with diameters ranging from 2 nm to several micrometres from polymer solutions or melts. Electrospinning of nanofibers subbiah 2005 journal. In 1873, plateau found experimentally that a vertically falling stream of water will break up into drops if its wavelength is greater than about 3.

Rayleigh instability and offaxis bending instability14. Overall, the studied instability peaks propagate with a velocity of 1. In 1873, joseph plateau rst studied the instability of. In the second, small perturbations induce bending instabilities, and a complex jet path is consequently observed. Progress of electrospray and electrospinning in energy.

It is written based on pro fessor tong lins syllabus to teach the nanotechnology majored stu dents at deakin university, australia, and postgraduate students who. Shin department of materials science and engineering, massachusetts institute of technology, cambridge, massachusetts 029 m. When the electrospun ps fibers are annealed on a polymethyl methacrylate pmmacoated substrate, a rayleighinstabilitydriven. Depending on the thickness of the underlying pmma films, the electrospun ps fibers may transform into hemispheres. Experiments and modelling of electrospinning process possible to follow the evolution of the jet shape. Plateaurayleigh instability, the bilayer film breaks up into individual droplets on the. Similarly to the standard electrospray, the application of high voltage to a polymer solution can result in the formation of a conejet geometry. A theoretical understanding of the physi cal mechanisms. After the jet flowed away from the droplet in a nearly straight line, it bent into a complex path and other changes in shape occurred, during which electrical forces stretched and thinned it by very large ratios. The basic principles for dealing with electrified fluids were published in a series of papers by taylor in the early 1960s 1, 2. Plateaurayleigh instability morphology evolution prime. Nichols and mullins later applied the rayleighs theory to.

Bending instability of electrically charged liquid jets of. In this system, the time scale is equal to the length scale divided by the jet speed. Prezentace aplikace powerpoint technical university of. This small oscillation increases as the fibre approach the collector forming what is known as whipping. Effects of electrospinning setup and process parameters on.

High voltage is applied to a liquid supplied through an emitter usually a glass or metallic capillary. The ejected jet may break into small droplets or particles due to the rayleigh instability as a result of low viscosity of solution,32 which results in the formation of beadsonstring. Ideally the liquid reaching the emitter tip forms a taylor cone, which emits a liquid jet through its apex. May 07, 2015 overall, the studied instability peaks propagate with a velocity of 1.